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Superbases for Organic Synthesis: Guanidines, Amidines, Phosphazenes and Related
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- Compralo SubitoSuperbases for Organic Synthesis: Guanidines, Amidines, Phosphazenes and Related
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Numero oggetto eBay:403959504610
Specifiche dell'oggetto
- Condizione
- Book Title
- Superbases for Organic Synthesis: Guanidines, Amidines, Phosphaze
- Publication Date
- 2009-03-02
- Pages
- 336
- ISBN
- 9780470518007
Informazioni su questo prodotto
Product Identifiers
Publisher
Wiley & Sons, Incorporated, John
ISBN-10
0470518006
ISBN-13
9780470518007
eBay Product ID (ePID)
70937106
Product Key Features
Number of Pages
336 Pages
Publication Name
Superbases for Organic Synthesis : Guanidines, Amidines, Phosphazenes and Related Organocatalysts
Language
English
Subject
Chemistry / Physical & Theoretical, Chemistry / Organic
Publication Year
2009
Type
Textbook
Subject Area
Science
Format
Hardcover
Dimensions
Item Height
1 in
Item Weight
25.5 Oz
Item Length
9.9 in
Item Width
6.9 in
Additional Product Features
Intended Audience
Scholarly & Professional
LCCN
2008-044058
Dewey Edition
22
Illustrated
Yes
Dewey Decimal
547/.2
Table Of Content
Preface. Acknowledgements. List of Contributors. 1. General Aspects of Organosuperbases (Tsutomu Ishikawa). 2. Physicochemical Properties of Organic Superbases (Davor Margetic). 2.1 Introduction. 2.2 Proton sponges. 2.3 Amidines. 2.4 Guanidines. 2.5 Phosphazenes. 2.6 Guanidinophosphazenes. 2.7 Other Phosphorus Containing Superbases: Verkade's Proazaphosphatranes. 2.8 Theoretical Methods. 2.9 Concluding Remarks. References. 3. Amidines in Organic Synthesis (Tsutomu Ishikawa and Takuya Kumamoto). 3.1 Introduction. 3.2 Preparation of Amidine. 3.3 Application of Amidines to Organic Synthesis. 3.4 Amidinium Salt: Design and Synthesis. 3.5 Concluding Remarks. References. 4. Guanidines in Organic Synthesis (Tsutomu Ishikawa). 4.1. Introduction. 4.2. Preparation of Chiral Guanidines. 4.3 Guanidines as Synthetic Tools. 4.4 Guanidinium Salt. 4.5 Concluding Remarks. References. 5. Phosphazene: Preparation, Reaction and Catalytic Role (Yoshinori Kondo). 5.1 Introduction. 5.2 Deprotonative Transformations Using Stoichiometric Phosphazenes. 5.3 Transformation Using Phosphazene Catalyst. 5.4 Proazaphosphatrane Base (Verkade's Base). 5.5 Concluding Remarks. References. 6. Polymer-supported Organosuperbases (Hiyoshizo Kotsuki). 6.1 Introduction. 6.2 Acylation reactions. 6.3 Alkylation Reactions. 6.4 Heterocyclization. 6.5 Miscellaneous. 6.6 Concluding Remarks. References. 7. Application of Organosuperbases to Total Synthesis (Kazuo Nagasawa). 7.1 Introduction. 7.2 Carbon-carbon bond-forming reactions. 7.3 Deprotection. 7.4 Elimination. 7.5 Ether synthesis. 7.6 Heteroatom conjugate addition. 7.7 Isomerization. 7.8 Concluding Remarks. References. 8. Related Organocatalysts (1): Proton Sponge (Kazuo Nagasawa). 8.1 Introduction. 8.2 Alkylation and Hetero Michael reaction. 8.3 Amide formation. 8.4 Carbon-carbon bond-forming reaction. 8.5 Palladium-catalyzed reaction. 8.6 Concluding Remarks. References. 9. Related Organocatalysts (2): Urea Derivatives (Waka Nakanishi). 9.1 Introduction. 9.2 Bisphenol as Organoacid Catalyst. 9.3 Urea and Thiourea as Achiral Catalysts. 9.4 Urea and Thiourea as Chiral Catalyst. 9.5 Concluding Remarks. References. 10. Amidines and Guanidines in Natural Products and Medicines (Takuya Kumamoto). 10.1 Introduction. 10.2 Natural Amidine Derivatives. 10.3 Natural Guanidine Derivatives. 10.4 Medicinal Amidine and Guanidine Derivatives. References. 11. Perspective (Tsutomu Ishikawa and Davor Margetic).
Synopsis
Guanidines, amidines and phosphazenes have been attracting attention in organic synthesis due to their potential functionality resulting from their extremely strong basicity. They are also promising catalysts because of their potential for easy molecular modification, possible recyclability, and reduced or zero toxicity. Importantly, these molecules can be derived as natural products - valuable as scientists move towards "sustainable chemistry", where reagents and catalysts are derived from biomaterial sources. Superbases for Organic Synthesis is an essential guide to these important molecules for preparative organic synthesis. Topics covered include the following aspects: an introduction to organosuperbases physicochemical properties of organic superbases amidines and guanidines in organic synthesis phosphazene: preparation, reaction and catalytic role polymer-supported organosuperbases application of organosuperbases to total synthesis related organocatalysts: proton sponges and urea derivatives amidines and guanidines in natural products and medicines Superbases for Organic Synthesis is a comprehensive, authoritative and up-to-date guide to these important reagents for organic chemists, drug discovery researchers and those interested in the chemistry of natural products., Guanidines, amidines and phosphazenes have been attracting attention in organic synthesis due to their potential functionality resulting from their extremely strong basicity. They are also promising catalysts because of their potential for easy molecular modification, possible recyclability, and reduced or zero toxicity.
LC Classification Number
QD262
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- _***b (56)- Feedback lasciato dall'acquirente.Mese scorsoAcquisto verificatoI gave 5 stars on shipping because i sent 2 separate emails + they responded with helpful info, even though it arrived late. This was a great value with free shipping + the condition is very good, better than advertised 🙂! The overall quality and appearance is excellent! I highly recommend this seller and give them 👍👍👍👍
- a***n (54)- Feedback lasciato dall'acquirente.Ultimi 6 mesiAcquisto verificatoMistakenly ordered a paperback that I thought was a hardcover, not sellers fault; it was described properly on the listing. Seller still processed a refund the day I went to return the item and let me keep the item anyway. A+++ service. Book arrived quickly in great condition and for a great price. Thank you so much! Amazing seller!